Publications while at the University of Maryland

  1. Wang, X.; Jayathilake, R.; Taylor, D. D.; Rodriguez, E. E, Zachariah, M. R, "Study of C/Doped d-Bi2O3 Redox Reactions by in Operando Synchrotron X-ray Diffraction: Bond Energy/Oxygen Vacancy and Reaction Kinetics Relationships", J. Phys. Chem. C, 2018, 122(16), 8796-8803. [Link, Cite]
  2. Zhou, X.; Wilfong, B.; Liou, S.-C., Hodovanets, H.; Brown C. M. and Rodriguez, E.E, "Proton and ammonia intercalation into layered iron chalcogenides", Chem. Comm., Accepted, DOI:10.1039/C8CC02436G. [Link, Cite]
  3. Stimpson, L. J.; Rodriguez, E. E.; Brown C. M.; Stenning, G. B. G.; Jura, M. and Arnold, D. C., "Magnetic ordering in a frustrated bow-tie lattice", J. Mater. Chem. C, 2018, 6, 4541-4548, [Link, Cite]
  4. Wilfong, B.; Zhou, X.; Vivanco, H.; Campbell, D.J.; Wang, K.; Graf, D.; Paglione, J.; and Rodriguez, E.E, "Frustrated magnetism in the tetragonal CoSe analog of superconducting FeSe", Phys. Rev. B., 2018, 97, 104408. [Link, Cite]
  5. Jayathilake, R.; Levitas, B.; Rodriguez, E. E, "In situ diffraction studies on reversible oxygen uptake and release in AFe2O4+δ (A = Lu, Yb, Y, In)", J. Mater. Chem. A., 2018, 6, 4801-4810 [Link, Cite]
  6. 2017
  7. Stock, C.; Rodriguez, E.E.; Lee, N.; Demmel, F.; Fouquet, P.; Laver, M.; Niedermayer, C.; Su, Y.; Nemkovski, K.; Green, M.A.; Rodriguez-Rivera, J.A.; Kim, J.W.; Zhang, L.; and Cheong, S.-W. "Orphan Spins in the S = 5/2 Antiferromagnet CaFe2O4", Phys. Rev. Lett., 2017, 119, 257204, [Link, Cite]
  8. Zhou, X.; Rodriguez, E. E., "Tetrahedral transition metal chalcogenides as functional inorganic materials", Chem. Mater., 2017, 29, 5737. [Link, Cite]
  9. Larson, A.; Wilfong, B.; Moetakef, P.; Brown, C. M.; Zavalij, P.; Rodriguez, E. E., "Metal–insulator transition tuned by magnetic field in Bi1.7V8O16 hollandite? Journal of Materials Chemistry C, 2017, 5, 4967", J. Mater. Chem. C, 2017, 5, 4967. [Link Cite]
  10. Zhou, X.; Eckberg, C.; Wilfong, B.; Liou, S.-C.; Vivanco, H. K.; Paglione, J.; Rodriguez, E. E., "Superconductivity in iron sulfides intercalated by metal hydroxides", Chem. Sci., 2017, 8, 3781. [Link, Cite]
  11. 2016
  12. Zhou, X.; Wilfong, B.; Vivanco, H. K.; Paglione, J.; Brown, C. M.; Rodriguez, E. E., "Layered metastable cobalt chalcogenides from topochemical deintercalation", J. Am. Chem. Soc., 2016, 138, 16432. [Link, Cite]
  13. Zhou, X.; Zhou, W.; Udovic, T. J.; Yildrim, T.; Rush, J. J.; Rodriguez, E. E.; Wu, H., "Development of potential organic-molecule-based hydrogen storage materials: Converting C-N bond-breaking thermolysis of guanidine to N-H bond-breaking dehydrogenation", Int. J. Hydrogen Energy, 2016, 41, 18542. [Link, Cite]
  14. Liu, L.; Taylor, D. D.; Rodriguez, E. E.; Zachariah, M. R., "Influence of transition metal electronegativity on the oxygen storage cpacity of perovskite oxides", Chem. Comm., 2016, 52, 10369-10372. [Link, Cite]
  15. Stock, C.; Rodriguez, E. E.; Lee, N. Green, M. A.; Demmel, R. A.; Ewings, R. A.; Fouquet, P.; Laver, M.; Niedermayer, Y. S.; Nemkovski, K.; Rodriguez-Rivera, J. A.; Cheong, S.-W., "Solitary Magnons in the S = 5/2 Antiferromagnet CaFe2O4", Phys. Rev. Lett., 2016, 117, 017201. [Link, Cite]
  16. Wu, H.; Zhou, X.; Rodriguez, E. E.; Zhou, W.; Udovic, T. J.; Yildrim, T.; Rush, J. J., "A new family of metal borohydride guanidinate complexes: Synthesis, structures and hydrogen-storage properties", J. Sol. State Chem., 2016, 242, 186. [Link, Cite]
  17. Taylor, Daniel D.; Schreiber, N.; Levitas, B.; Xu, W.; Whitfield, P.; Rodriguez, E. E., "Oxygen storage properties of La1-xSrxFeO3-δ for chemical-looping reactions - an in-situ neutron and synchrotron X-ray study", Chem. Mater., 2016, 28, 3951-3960. [Link, Cite]
  18. Vivanco, H. K. and Rodriguez, E. E., "The intercalation chemistry of layered iron chalcogenide superconductors", J. Sol. State Chem., 2016, 242, 3-21 [LinkCite]
  19. Borg, C. K. H.; Zhou, X.; Eckberg, C.; Campbell, D. J.; Saha, S. R.; Paglione, J.; Rodriguez, E. E., "Strong anisotropy in nearly ideal tetrahedral superconducting FeS single crystals.", Phys. Rev. B, 2016, 93, 094522. [Link, Cite]
  20. Zhou, X.; Borg, C. K. H.; Lynn, J. W.; Saha, S. R.; Paglione, J.; Rodriguez, E. E., "The preparation and phase diagrams of (7Li1-xFexOD)FeSe and (Li1-xFexOH)FeSe superconductors.", J. Mater. Chem. C, 2016, 4, 3934. [Link, Cite]
  21. Rodriguez, E. E.; Cao, H.; Haiges, R.; Melot, B. C., "Single crystal magnetic structure and susceptibility of CoSe2O5.", J. Sol. State Chem., 2016, 236, 39. [Link, Cite]
  22. 2015
  23. Moetakef, P.; Wang, L.; Maughan, A. E.; Gaskell, K. J.; Larson, A. M.; Hodges, B. C.; Rodriguez, E. E., "Tuning the electronic band structure of microporous titanates with the hollandite structure.", J. Mater. Chem. A, 2015, 3, 20330. [Link, Cite]
  24. Lynn, J. W.; Zhou, X.; Borg, C. K. H.; Saha, S. R.; Paglione, J.; Rodriguez, E. E., "Neutron investigation of the magnetic scattering in an iron-based ferromagnetic superconductor.", Phys. Rev. B, 2015, 92, 060510(R). [Link, Cite]
  25. Taylor, D. D.; Schreiber, N. J.; Brown, C. M.; Arevalo-Lopez, A. M.; Rodriguez, E. E., "Stabilization of cubic Sr2FeMoO6 through topochemical reduction.", Chem. Commun., 2015, 51, 12201. [Link, Cite]
  26. Stock, C.; Rodriguez-Rivera, J. A.; Schmalzl, K.; Rodriguez, E. E.; Stunault, A.; Petrovic, C., "Single to Multiquasiparticle Excitations in the Itinerant Helical Magnet CeRhIn5", Phys. Rev. Lett., 114, 247005 [Link, Cite]
  27. Lennox, R. C.; Taylor, D. D.; Vera Stimpson, L. J.; Stenning, G. B. G; Jura, M.; Price, M. C.; Rodriguez, E. E.; Arnold, D. C. "ZT-like structural phase transitions in the BiFeO3 - KNbO3 solid solution", Dalton Trans., 2015, 44, 10608 - 10613 [Link, Cite]
  28. Larson, A. M.; Moetakef, P.; Brown, C.; Gaskell, K.; King, G.; Rodriguez, E. E., "Inducing ferrimagnetism in insulating hollandite Ba1.2Mn8O16", Chem. Mater. 2015, 27, 515-525. [Link, Cite]
  29. Phelan, D.; Rodriguez, E. E.; Bing, Y.; Gao, J.; Ye, Z.; Huang, Q.; Wen, J.; Xu, G.; Stock, C.; Matsuura, M.; Gehring, P. M. "Phase diagram of the relaxor ferroelectric (1-x)Pb(Mg1/3Nb2/3)O3+xPbTiO3: A neutron powder diffraction study of the relaxor skin effect.", Phase Transit., 2015, 88, 283-305. [Link, Cite]
  30. 2014
  31. Moetakef, P.; Larson, A. M.; Hodges, B.; Zavalij, P. J.; Gaskell, K. J.; Piccoli, P.; Rodriguez, E. E., "Synthesis and crystal chemistry of microporous titanates Kx(Ti,M)8O16 where M = Sc-Ni.", J. Sol. State Chem., 2014, 220, 45. [Link, Cite]
  32. Stacey, T. E.; Borg, C. K. H.; Zavalij, P. J.; Rodriguez, E. E., "Magnetically Stabilized Fe84-S)6S8 Clusters in Ba6Fe25S27", Dalton Trans., 2014, 43, 14612. [Link, Cite]
  33. McCabe, E. E.; Stock, C.; Rodriguez, E. E.; Wills, A. S.; Taylor, J. W.; Evans, J. S. O., "Weak spin interactions in Mott insulating La2O2Fe2OSe2", Phys. Rev. B, 2014, 89, 100402(R). [Link, Cite]
  34. 2013
  35. Rondinelli, J. M.; Benedek, N. A.; Freedman, D. E.; Kavner, A.; Rodriguez, E. E.; Toberer, E. S.; Martin, L. W., "Accelerating functional materials discovery", Am. Ceram. Soc. Bull., 2013, 92, 14-2. [Cite]
  36. Johnstone, E. V.; Poineau, F.; Starkey, J.; Hartmann, T.; Forster, P.M.; Ma, L.; Hilgar, J.; Rodriguez, E. E.; Farmand, R.; Czerwinski, K. R.; Sattelberger, A. P., "Synthetic and Coordination Chemistry of the Heavier Trivalent Technetium Binary Halides: Uncovering Technetium Triiodide", Inorg. Chem., 2013, 52, 14309. [Link, Cite]
  37. Gaultois, M. W.; Barton, P. T.; Birkel, C. S.; Misch, L. M.; Rodriguez, E. E., Stucky, G. D., Seshadri, R., "Structural disorder, magnetism, and electrical and thermoelectric properties of pyrochlore Nd2Ru2O7", J. Phys: Condens. Matter, 2013, 25 186004-1-10. [Link, Cite]
  38. Publications before the University of Maryland
  39. Stock, C.; Rodriguez, E. E.; Sobolev, O.; Rodriguez-Rivera, J. A.; Ewings, R. A.; Taylor, J. W.; Christianson, A. D.; Green, M. A. "Soft striped magnetic fluctuations competing with superconductivity in Fe1+xTe.", Phys. Rev. B, 2014, 90, 121113(R). [Link, Cite]
  40. Rodriguez, E. E.; Sokolov, D. A.; Green, M. A.; Sobolev, O.; Rodriguez-Rivera, J. A.; Cao, H.; Daoud-Aladine, A., "Magnetic and structural properties near the Lifshitz point in Fe1+xTe", Phys. Rev. B, 2013, 88 165110-1-5. Link, Cite]
  41. Blachowski, A.; Ruebenbauer, K.; Zajdel, P.; Rodriguez, E. E.; Green, M. A., "Mössbauer study of the '11' iron-based superconductors parent compound Fe1+xTe", J. Phys.: Condens. Matter, 2012, 24, 386006. [Link, Cite]
  42. Stock, C.; Rodriguez, E. E.; Green, M. A., "Spin fluctuations and superconductivity in powders of Fe1+xTe0.7Se0.3", Phys. Rev. B, 2012, 85, 094507. [Link, Cite]
  43. Bhatia, V.; Rodriguez, E. E.; Butch N. P.; Paglione, J.; Green, M. A., "Phase separation and superconductivity in Fe1+xTe0.5Se0.5", Chem. Comm., 2011, 47, 11297. [Link, Cite]
  44. Rodriguez, E. E.; Stock, C.; Hsieh, P.-Y.; Butch, N. P.; Paglione, J; Green, M. A., "Interstitial iron-controlled superconductivity in Fe1+xTe0.7Se0.3", Chem. Sci., 2011, 2, 1782. [Link, Cite]
  45. Stock, C.; Rodriguez, E. E.; Green, M. A.; Rodriguez-Rivera, J. A., "Gapped spin fluctuations and interstitial iron in the Fe1+xTe parent compound", Phys. Rev. B, 2011, 84, 045124. [Link, Cite]
  46. Rodriguez, E. E.; Stock, C.; Zajdel, P.; Krycka, K. L.; Majkrzak, C. F.; Zavalij, P.; Green, M. A., "Magnetic-crystallographic phase diagram of the superconducting parent compound Fe1+xTe", Phys. Rev. B, 2011, 84, 064403. [Link, Cite]
  47. Rodriguez, E. E.; Stock, C.; Krycka, K. L; Majkrzak, C. F.; Kirshenbaum, K.; Butch, N. P.; Saha, S. R.; Paglione, J.; Green, M. A., "Non-collinear spin-density wave antiferromagnetism in FeAs", Phys. Rev. B, 2011, 83, 134438. [Link, Cite]
  48. Rodriguez, E. E.; Poineau, F.; Llobet, A.; Kennedy, B. J.; Avdeev, M.; Thorogood, G. J.; Carter, M. L.; Singh, D. J.; Seshadri, R.; Cheetham, A. K, "High temperature magnetic ordering in the 4d perovskite SrTcO3", Phys. Rev. Lett., 2011, 106, 067201. [Link, Cite]
  49. Rodriguez, E. E.; Poineau, F.; Llobet, A.; Thompson, J. D.; Seshadri, R.; Cheetham, A. K, "Preparation, magnetism and electronic structures of cadmium technetates", J. Mater. Chem., 2011, 21, 1496. [Link, Cite]
  50. Zajdel, P.; Hsieh, P.-Y.; Rodriguez, E. E.; Butch, N. P.; Magill, J. D.; Paglione, J.; Zavalij, P.; Suchomel, M. R.; Green, M. A., "Phase separation and suppression of the structural and magnetic transitions in superconducting doped iron tellurides Fe1+xTe1-ySy", J. Am. Chem. Soc., 2010, 132, 13000. [Link, Cite]
  51. Rodriguez, E. E.; Zavalij, P.; Hsieh, P.-Y.; Green, M. A., "Iodine as an oxidant in the topotactic deintercalation of Fe1+xTe", J. Am. Chem. Soc., 2010, 132, 10006. [Link, Cite]
  52. Melot, B. C.; Darago, L. E.; Seshadri, R.; Goldman, A.; Furman, J. D.; Rodriguez, E. E.; "Magnetic ordering and magnetodielectric phenomena in CoSeO4", J. Phys.: Cond. Matter, 2010, 22, 506003. [Link, Cite]
  53. Weck, P. F.; Kim, E.; Poineau, F.; Rodriguez, E. E.; Sattelberger, A. P.; Czerwinski, K. R. "Structural and electronic trends in rare-earth technetates", Dalton Trans., 2010, 39, 7207. [Link, Cite]
  54. Rodriguez, E. E.; Llobet, A.; Proffen, Th.; Melot, B. C.; Seshadri, R.; Littlewood, P. B.; Cheetham, A. K, "The role of static disorder in negative thermal expansion in ReO3", J. Appl. Phys., 2009, 109, 114901. [Link, Cite]
  55. Poineau, F.; Rodriguez, E. E.; Forster, P. M.; Sattelberger, A. P.; Cheetham, A. K; Czerwinski, K. R., "Preparation of the binary technetium bromides: TcBr3 and TcBr4", J. Am. Chem. Soc., 2009, 131, 6281. [Link, Cite]
  56. Wilcox, J. D.; Rodriguez, E. E.; Doeff, M. M., "The impact of aluminum and iron substitution on the structure and electrochemistry of Li(Ni0.4Co0.2-yMyMn0.4)O2 materials", J. Electrochem. Soc., 2009, 156, A1011. [Link, Cite]
  57. Shoemaker, D.; Rodriguez, E. E.; Abumohor, I. S.; Proffen, Th.; Seshadri, R.; "Intrinsic exchange bias in ZnxMn3-xO4 solid solutions", Phys. Rev. B, 2009, 80, 144422. [Link, Cite]
  58. Weck, P. F.; Kim, E.; Poineau, F.; Rodriguez, E. E.; Sattelberger, A. P.; Czerwinski, K. R., "Technetium (IV) halides predicted by first-principles", Inorg. Chem., 2009, 48, 6555. Link, Cite]
  59. Rodriguez, E. E.; Poineau, F.; Llobet, A.; Czerwinski, K. R.; Seshadri, R.; and Cheetham, A. K, "Preparation and crystal structures of bismuth technetates: a new metal oxide system", Inorg. Chem., 2008, 47, 6281. [Link, Cite]
  60. Rodriguez, E. E.; Poineau, F.; Llobet, A.; Sattelberger, A. P.; Bhattacharjee, J.; Waghmare, U. V.; Hartmann, T.; Cheetham, A. K, "Structural studies of TcO2 by neutron powder diffraction and first-principles calculations", J. Am. Chem. Soc., 2007, 129, 10244. [Link, Cite]
  61. Melot, B.; Rodriguez, E.; Proffen, Th.; Hayward, M. A.; Seshadri, R., "Displacive disorder in three high-k bismuth oxide pyrochlores", Mat. Res. Bull., 2006, 41, 961. [Link, Cite]
  62. Rodriguez, E. E.; Proffen, Th.; Llobet, A.; Mitchell, J. F.; Rhyne, J. J., "Neutron diffraction study of the average and local structure of La0.5Ca0.5MnO3", Phys. Rev. B, 2005, 71, 104430. [Link, Cite]
  63. Ross, C.A.; Castaño, T.; Rodriguez, E.; Haratani, S.; Vögeli, B.; Smith, H. I., "Size- dependent switching of multilayer magnetic elements", J. Appl. Phys., 2005, 97, 053902. [Link, Cite]
  64. Marioni, M.; Bono, D.; Banful, A.B.; del Rosario, M.; Rodriguez, E.; Peterson, B.; Allen, S.M.; O’Handley, R.C., "Pulsed field actuation of Ni-Mn-Ga ferromagnetic shape memory alloy single crystal", J. Phys. IV (Paris), 2003, 112, 1001. [Link, Cite]